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Advanced Semiconductor Physics

15.1 MOSFET Operation in Detail

In an n-channel MOSFET, the gate voltage VGV_G controls the channel charge:

Threshold voltage:

VT=VFB+2ϕF+2εsqNA(2ϕF)CoxV_T = V_{FB} + 2\phi_F + \frac{\sqrt{2\varepsilon_s q N_A(2\phi_F)}}{C_{ox}}

Where VFBV_{FB} is the flat-band voltage, ϕF=(kBT/q)ln(NA/ni)\phi_F = (k_BT/q)\ln(N_A/n_i) is the bulk Fermi potential, and Cox=εox/toxC_{ox} = \varepsilon_{ox}/t_{ox} is the oxide capacitance.

Drain current (long-channel, above threshold):

ID=μnCoxWL[(VGVT)VDVD22](linear region)I_D = \mu_n C_{ox}\frac{W}{L}\left[\left(V_G - V_T\right)V_D - \frac{V_D^2}{2}\right] \quad \text{(linear region)}

I_D = \frac{1}{2}\mu_n C_{ox}\frac{W}{L}(V_G - V_T)^2 \quad \text{(saturation, V_D \geq V_G - V_T \text{)}}

Subthreshold swing: Below threshold, the current decreases exponentially:

IDeqVG/(nkBT)I_D \propto e^{qV_G/(nk_BT)}

Where n=1+Cd/Coxn = 1 + C_d/C_{ox} and CdC_d is the depletion capacitance. The minimum subthreshold swing at room temperature is S=nkBTln10/q60S = nk_BT\ln 10/q \approx 60 mV/decade.

15.2 Bipolar Junction Transistor (BJT)

A BJT consists of three semiconductor regions: emitter (E), base (B), collector (C). In active mode (E-B forward biased, C-B reverse biased):

Ebers—Moll model:

IE=IES(eVBE/VT1)αRICS(eVBC/VT1)I_E = I_{ES}\left(e^{V_{BE}/V_T} - 1\right) - \alpha_R I_{CS}\left(e^{V_{BC}/V_T} - 1\right)

IC=αFIES(eVBE/VT1)ICS(eVBC/VT1)I_C = \alpha_F I_{ES}\left(e^{V_{BE}/V_T} - 1\right) - I_{CS}\left(e^{V_{BC}/V_T} - 1\right)

Where αF\alpha_F is the forward current gain ( 0.980.980.9980.998) and VT=kBT/eV_T = k_BT/e.

The common-emitter current gain β=αF/(1αF)\beta = \alpha_F/(1 - \alpha_F). For αF=0.99\alpha_F = 0.99: β=99\beta = 99.

15.3 Excitons and Polaritons

Wannier—Mott excitons (in semiconductors with small εr\varepsilon_r and small effective mass):

En=Egμe42(4πε0εr)22n2=EgRn2E_n = E_g - \frac{\mu e^4}{2(4\pi\varepsilon_0\varepsilon_r)^2\hbar^2 n^2} = E_g - \frac{R^*}{n^2}

Where R=μmeεr2×13.6R^* = \frac{\mu}{m_e\varepsilon_r^2} \times 13.6 eV is the effective Rydberg.

For GaAs (me=0.067mem_e^* = 0.067m_e, mh=0.45mem_h^* = 0.45m_e, εr=12.9\varepsilon_r = 12.9):

μ=0.067×0.450.067+0.45me=0.058me\mu = \frac{0.067 \times 0.45}{0.067 + 0.45}m_e = 0.058m_e

R=0.05812.92×13.6=0.058166.4×13.6=4.7 meVR^* = \frac{0.058}{12.9^2} \times 13.6 = \frac{0.058}{166.4} \times 13.6 = 4.7\ \text{meV}

aB=εrmeμa0=12.90.058×0.529 A˚ = 118 A˚ \approx12 nma_B^* = \frac{\varepsilon_r m_e}{\mu}a_0 = \frac{12.9}{0.058} \times 0.529\ \text{Å = 118\ \text{Å \approx 12\ \text{nm}}}

The large exciton Bohr radius means excitons are dissociated by thermal energy at room temperature in most semiconductors.

Polaritons form when excitons strongly couple to photons in a microcavity, producing hybrid light-matter quasiparticles with dispersion:

E_{\pm}(k) = \frac{1}{2}\left(E_{\text{cav}(k) + E_{\text{exc}(k)\right) \pm \frac{1}{2}\sqrt{\Omega_R^2 + \delta^2(k)}}}

Where ΩR\Omega_R is the Rabi splitting and δ=EcavEexc\delta = E_{\text{cav} - E_{\text{exc}}} is the detuning.

Worked Example 15.1: MOSFET Drain Current

An n-channel MOSFET has μn=450\mu_n = 450 cm2^2/(V\cdotS), Cox=34.5C_{ox} = 34.5 nF/cm2^2 (tox=10t_{ox} = 10 nm SiO2_2), W=10W = 10 μ\muM, L=1L = 1 μ\muM, VT=0.7V_T = 0.7 V.

For VG=2V_G = 2 V, VD=0.5V_D = 0.5 V (linear region since VD<VGVT=1.3V_D < V_G - V_T = 1.3 V):

ID=450×34.5×109×10×1041×104[1.3×0.50.252]I_D = 450 \times 34.5 \times 10^{-9} \times \frac{10 \times 10^{-4}}{1 \times 10^{-4}}\left[1.3 \times 0.5 - \frac{0.25}{2}\right]

=450×3.45×107×10×[0.650.125]= 450 \times 3.45 \times 10^{-7} \times 10 \times [0.65 - 0.125]

=1.55×103×0.525=8.14×104 A=0.814 mA= 1.55 \times 10^{-3} \times 0.525 = 8.14 \times 10^{-4}\ \text{A} = 0.814\ \text{mA}

At saturation (VD=2V_D = 2 V):

ID=12×450×34.5×109×10×(1.3)2=1.30 mAI_D = \frac{1}{2} \times 450 \times 34.5 \times 10^{-9} \times 10 \times (1.3)^2 = 1.30\ \text{mA}

Common Pitfalls (Additional)

  1. GL theory is valid only near TcT_c: The Ginzburg—Landau theory is a mean-field expansion that assumes the order parameter varies slowly in space and is small. It cannot describe the full temperature range or the strong-coupling limit. BCS theory provides the microscopic justification for the GL phenomenological parameters.

  2. Topological invariants are robust but not invincible: Topological surface states are protected against disorder that preserves the underlying symmetry (e.g., time-reversal for Z2Z_2 TIs). Breaking that symmetry (e.g., magnetic doping of a TI) can gap out the surface states. Similarly, interactions can sometimes destroy topological phases.

  3. Hubbard UU is not the bare Coulomb energy: The effective UU in the Hubbard model is significantly reduced from the bare Coulomb repulsion (20\sim 20 eV for 3d3d electrons) by screening. Typical values are U2U \sim 288 eV for transition metal oxides.

  4. MOSFET scaling limits: As transistors shrink below 10\sim 10 nm, short-channel effects (drain-induced barrier lowering, punch-through) dominate, and the subthreshold swing cannot be reduced below 60 mV/decade with conventional thermionic emission. This motivates research into tunnel FETs and other steep-slope devices.

  5. Effective mass can be negative or anisotropic: The curvature d2ε/dk2d^2\varepsilon/dk^2 determines the sign of mm^*. Near band maxima, m<0m^* < 0 (holes). In multivalley semiconductors like silicon, the effective mass tensor has longitudinal (mlm_l) and transverse (mtm_t) components that differ significantly (ml/mt5m_l/m_t \approx 5 for Si).

Problems (Additional)

Problem 19: GL Coherence Length and Penetration Depth

A Type II superconductor has ξ0=5\xi_0 = 5 nm and λ0=50\lambda_0 = 50 nm at T=0T = 0. At T=0.9TcT = 0.9\,T_c:

(a) Calculate ξ(T)\xi(T), λ(T)\lambda(T)And κ(T)\kappa(T).

(b) Calculate Bc1B_{c1} and Bc2B_{c2} at T=0.9TcT = 0.9\,T_c.

(c) How many flux quanta per unit area are present at B=Bc2/2B = B_{c2}/2?

Solution:

(a) At T=0.9TcT = 0.9\,T_c: 1T/Tc=0.11 - T/T_c = 0.1.

ξ=ξ00.1=50.316=15.8 nm,λ=500.1=158 nm\xi = \frac{\xi_0}{\sqrt{0.1}} = \frac{5}{0.316} = 15.8\ \text{nm}, \quad \lambda = \frac{50}{\sqrt{0.1}} = 158\ \text{nm}

κ=λ/ξ=10(independent of T)\kappa = \lambda/\xi = 10 \quad \text{(independent of T\text{)}}

(b) Bc2=Φ02πξ2=2.07×10152π×(15.8×109)2=2.07×10151.57×1015=1.32 TB_{c2} = \frac{\Phi_0}{2\pi\xi^2} = \frac{2.07 \times 10^{-15}}{2\pi \times (15.8 \times 10^{-9})^2} = \frac{2.07 \times 10^{-15}}{1.57 \times 10^{-15}} = 1.32\ \text{T}

Bc1=Φ04πλ2lnκ=2.07×10154π×(158×109)2ln10=2.07×10153.14×1013×2.303=1.52×103 T=1.52 mTB_{c1} = \frac{\Phi_0}{4\pi\lambda^2}\ln\kappa = \frac{2.07 \times 10^{-15}}{4\pi \times (158 \times 10^{-9})^2}\ln 10 = \frac{2.07 \times 10^{-15}}{3.14 \times 10^{-13}} \times 2.303 = 1.52 \times 10^{-3}\ \text{T} = 1.52\ \text{mT}

(c) At B=Bc2/2=0.66B = B_{c2}/2 = 0.66 T: number of flux quanta per m2^2 = B/Φ0=0.66/(2.07×1015)=3.19×1014 m2B/\Phi_0 = 0.66/(2.07 \times 10^{-15}) = 3.19 \times 10^{14}\ \text{m}^{-2}.

Average spacing between vortices: a(2Φ0/(3B))1/2=(2×2.07×1015/(1.73×0.66))1/2=60 nma \approx (2\Phi_0/(\sqrt{3}B))^{1/2} = (2 \times 2.07 \times 10^{-15}/(1.73 \times 0.66))^{1/2} = 60\ \text{nm}.

Problem 20: Berry Phase in a Tight-Binding Model

Consider a spinless particle on a 1D lattice with Hamiltonian:

H^=n(teiϕc^nc^n+1+teiϕc^n+1c^n)\hat{H} = \sum_n \left(t\,e^{i\phi}\,\hat{c}_n^\dagger\hat{c}_{n+1} + t\,e^{-i\phi}\,\hat{c}_{n+1}^\dagger\hat{c}_n\right)

(a) Show that the dispersion is ε(k)=2tcos(k+ϕ)\varepsilon(k) = -2t\cos(k + \phi).

(b) Calculate the Berry phase for an electron traversing the Brillouin zone π/aπ/a-\pi/a \to \pi/a.

(c) Show that the Berry phase is γ=2πϕ/(2π/a)\gamma = 2\pi\phi/(2\pi/a) and interpret physically.

Solution:

(a) Substituting ψk(n)=eikna/N\psi_k(n) = e^{ikna}/\sqrt{N}:

ε(k)ψk(n)=teiϕeikaψk(n)+teiϕeikaψk(n)\varepsilon(k)\psi_k(n) = t\,e^{i\phi}\,e^{ika}\psi_k(n) + t\,e^{-i\phi}\,e^{-ika}\psi_k(n)

ε(k)=tei(k+ϕ)a+tei(k+ϕ)a=2tcos(k+ϕ)\varepsilon(k) = t\,e^{i(k+\phi)a} + t\,e^{-i(k+\phi)a} = -2t\cos(k + \phi)

(b) The Bloch function is uk(n)=eiϕnu_k(n) = e^{i\phi n} (up to normalisation). The Berry connection:

A(k)=ukikuk=iiϕ=ϕA(k) = \langle u_k | i\partial_k | u_k \rangle = i \cdot i\phi = -\phi

Wait, more carefully. In a continuum formulation:

A(k)=ukkuk=k(arguk)=k(0)=0A(k) = \langle u_k | \frac{\partial}{\partial k} | u_k \rangle = \frac{\partial}{\partial k}(\arg u_k) = \frac{\partial}{\partial k}(0) = 0

Since uk(x)=eikxu_k(x) = e^{ikx} has klnuk=ix\partial_k \ln u_k = ix and ukixuk\langle u_k|ix|u_k\rangle averages to zero.

Actually, for this model the Berry phase arises from the ϕ\phi-dependent phase winding. Let us use the proper formulation. The wavefunction ψk(x)=eikxuk(x)\psi_k(x) = e^{ikx}u_k(x) where uku_k has the periodicity of the lattice. With the flux ϕ\phiThe Berry connection picks up an extra term. The Berry phase for one circuit of the BZ is:

γ=A(k)dk=2πϕ\gamma = \oint A(k)\,dk = 2\pi\phi

(c) The Berry phase γ=2πϕ\gamma = 2\pi\phi is directly proportional to the flux ϕ\phi per unit cell. This is the Aharonov—Bohm effect in a lattice: the flux threading each plaquette shifts the band minimum and modifies the group velocity. For ϕ=π\phi = \piThe band is inverted (ε=2tcosk\varepsilon = 2t\cos k), which is the basis for the Rice—Mele model of topological insulators.

Problem 21: Semiconductor Device Analysis

A silicon p-n junction has NA=1024N_A = 10^{24} m3^{-3} and ND=1022N_D = 10^{22} m3^{-3} at T=300T = 300 K.

(a) Calculate the built-in potential V0V_0.

(b) Calculate the depletion width WW and the depletion capacitance per unit area at zero bias.

(c) Under forward bias V=0.5V = 0.5 V, calculate the current density. Assume I0/A=1012I_0/A = 10^{-12} A/m2^2.

(d) What is the breakdown voltage if the critical field for Zener breakdown in Si is Ecrit3×108E_{\text{crit} \approx 3 \times 10^8} V/m?

Solution:

(a) V0=kBTelnNANDni2=0.02585×ln1024×1022(1.5×1016)2V_0 = \frac{k_BT}{e}\ln\frac{N_A N_D}{n_i^2} = 0.02585 \times \ln\frac{10^{24} \times 10^{22}}{(1.5 \times 10^{16})^2}

=0.02585×ln10462.25×1032=0.02585×ln(4.44×1013)= 0.02585 \times \ln\frac{10^{46}}{2.25 \times 10^{32}} = 0.02585 \times \ln(4.44 \times 10^{13})

=0.02585×31.43=0.812 V= 0.02585 \times 31.43 = 0.812\ \text{V}

(b) W=2εsV0e(1NA+1ND)W = \sqrt{\frac{2\varepsilon_s V_0}{e}\left(\frac{1}{N_A} + \frac{1}{N_D}\right)}

Since NDNAN_D \ll N_AThe depletion region extends mainly into the n-side:

W2×11.7×8.85×1012×0.8121.6×1019×1022=1.68×10101.6×103=1.05×107=3.24×104 m=0.324 mmW \approx \sqrt{\frac{2 \times 11.7 \times 8.85 \times 10^{-12} \times 0.812}{1.6 \times 10^{-19} \times 10^{22}}} = \sqrt{\frac{1.68 \times 10^{-10}}{1.6 \times 10^{-3}}} = \sqrt{1.05 \times 10^{-7}} = 3.24 \times 10^{-4}\ \text{m} = 0.324\ \text{mm}

This is a wide depletion region because of the asymmetric doping.

C/A=εsW=11.7×8.85×10123.24×104=3.19×107 F/m2=319 nF/m2C/A = \frac{\varepsilon_s}{W} = \frac{11.7 \times 8.85 \times 10^{-12}}{3.24 \times 10^{-4}} = 3.19 \times 10^{-7}\ \text{F}/m^2 = 319\ \text{nF}/m^2

(c) J=J0(eeV/(kBT)1)=1012(e0.5/0.025851)=1012(e19.341)=1012×2.48×108=2.48×104 A/m2=0.248 mA/m2J = J_0(e^{eV/(k_BT)} - 1) = 10^{-12}(e^{0.5/0.02585} - 1) = 10^{-12}(e^{19.34} - 1) = 10^{-12} \times 2.48 \times 10^8 = 2.48 \times 10^{-4}\ \text{A}/m^2 = 0.248\ \text{mA}/m^2

(d) The maximum field occurs at the metallurgical junction and for a one-sided junction is approximately Emax=2V0/WE_{\max} = 2V_0/W. For breakdown: VBDEcritWBD/2V_{BD} \approx E_{\text{crit} \cdot W_{BD}/2}.

With WBD=2εsVBD/(eND)W_{BD} = \sqrt{2\varepsilon_s V_{BD}/(eN_D)} (one-sided):

V_{BD} = \frac{\varepsilon_s E_{\text{crit}^2}{2eN_D} = \frac{11.7 \times 8.85 \times 10^{-12} \times (3 \times 10^8)^2}{2 \times 1.6 \times 10^{-19} \times 10^{22}} = \frac{9.29 \times 10^{-1}}{3.2 \times 10^{-3}} = 290\ \text{V}}